Catalysts for lean burn engine exhaust abatement

ABSTRACT

The present invention provides a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by contacting the gas stream under conditions effective to catalytically reduce the nitrogen oxides with a catalyst comprising a aluminum-silicate type material and a minor amount of a metal, the catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 60 percent under temperatures within the range of from about 200° C. to about 400° C.

BENEFIT OF PRIOR APPLICATION

[0001] This application claims the benefit of the filing date of U.S. Provisional Appplication 60/162,431, filed Oct. 28, 1999.

FIELD OF THE INVENTION

[0002] The present invention relates to catalysts for lean burn engine exhaust abatement and to processes for preparation of such catalysts. This invention was made with government support under Contract No. W-7405-ENG-36 awarded by the U.S. Department of Energy.

[0003] The government has certain rights in the invention.

BACKGROUND OF THE INVENTION

[0004] Removal of NO_(x) from exhaust streams is a critical technology for the automotive and electric power industry in meeting ever more stringent air emissions standards. In view of future emissions standards automotive companies have focused on the design of lean-burn engine designs where the combustion fuel to air ratio is substantially less than the stoichiometric ratio used in present day engines. Under lean burn conditions, the existing catalytic converter technology does not work. Thus, new catalytic converters must be developed for lean burn engine technology to be implemented. Lean burn deNO_(x) catalysts are highly sought after and are the focus of considerable research worldwide. A rather narrow window of satisfactory operating temperatures has characterized most catalysts for lean burn applications. Specifically, they only effectively convert NO_(x) over small temperature ranges that do not always match the temperatures at which the NO_(x) is emitted. Some of the better catalyst materials have included metal-substituted zeolite catalysts such as Cu-ZSM-5 and related catalysts consisting of various zeolites with metal ions substituted into the zeolite structure. These materials offer activity at higher temperatures than conventional platinum-based deNO_(x) catalysts, but the best operating temperature ranges are generally too high (above about 400° C.) and too narrow (only about 100° C. in effective range width).

[0005] In addition, internal combustion engines emit a large amount of unburned hydrocarbons during cold engine start-up. In fact, a rather large fraction of the total emitted hydrocarbons released during the first minutes of engine operation are due to the uncombusted hydrocarbons in the rich fuel mixture. Such release of hydrocarbons after engine start-up poses a special problem, as at that point the temperatures of the exhaust gas and the catalytic converter are generally not high enough for conversion of the gaseous pollutants by conventional catalysts. The catalysts in present catalytic converter systems are generally ineffective at ambient temperatures and must reach high temperatures, often in the range of 300° C. to 400° C. before they become effective.

[0006] For example, U.S. Pat. No. 5,171,553 describes the catalytic decomposition of N₂O from gaseous mixtures, but conversion or decomposition rates of 50 percent of the N₂O are shown as requiring temperatures of greater than about 275° C. as shown in their FIG. 3 for rhodium-exchanged zeolites and of greater than about 350° C. as shown in their FIGS. 1 and 2 for copper- and cobalt-exchanged zeolites.

[0007] U.S. Pat. No. 5,776,423 describes the catalytic decomposition of NO_(x) from gaseous mixtures, but shows conversion or decomposition rates of less than 50 percent of the NO_(x) at temperatures of less than about 375° C. even before aging of the catalyst as shown in their FIG. 1.

[0008] Numerous other patents such as U.S. Pat. No. 5,935,529, U.S. Pat. No. 5,869,013, U.S. Pat. No. 5,834,395, U.S. Pat. No. 5,695,728, U.S. Pat. No. 5,449,504, U.S. Pat. No. 5,443,803, U.S. Pat. No. 5,427,753, U.S. Pat. No. 5,358,916, U.S. Pat. No. 5,260,043, and U.S. Pat. No. 5,171,553, either describe the problems of treating exhaust gases at temperatures below 300° C. to 400° C. or fail to show conversion rates of 50 percent or more at temperatures below about 300° C. to 400° C.

[0009] Catalysts have now been found which overcome these obstacles and provide for effective NO_(x) conversion at lower temperatures and a wider temperature range.

[0010] It is an object of this invention to provide a process for NO_(x) conversion in an exhaust stream under temperature conditions of from about 200° C. to about 600° C.

[0011] Another object of this invention is a process for NO_(x) conversion of at least about 60 percent in an exhaust stream under temperature conditions of from about 200° C. to about 600° C., especially from about 200° C. to about 400° C.

[0012] Yet another object of the present invention is to provide for NO_(x) conversion in an exhaust stream with a broad effective operating range, i.e., a high conversion rate such as at least about 60 percent for a temperature range of greater than 200° C., preferably greater than 300° C.

[0013] Still another object of the present invention is to provide compositions of matter useful for the catalytic reduction of nitrogen oxides in an exhaust stream under temperature conditions of from about 200° C. to about 600° C., especially from about 200° C. to about 400° C.

SUMMARY OF THE INVENTION

[0014] To achieve the foregoing and other objects, and in accordance with the purposes of the present invention, as embodied and broadly described herein, provides a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material including contacting said gas stream under conditions effective to catalytically reduce said nitrogen oxides with a catalyst comprising a aluminum-silicate type material and a minor amount of a metal, said catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 60 percent under temperatures within the range of from about 200° C. to about 400° C.

[0015] The present invention further provides a composition of matter, useful in a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material, comprising a ferrierite material having undergone a pretreatment by contact with a dilute solution of a material selected from the group consisting of ammonium fluoride, ammonium nitrate, ammonium chloride, nitric acid, hydrochloric acid, hydrofluoric and oxalic acid for a sufficient period of time to allow for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by at least 60 percent under temperatures within the range of from about 200° C. to about 600° C. Such pretreatment is conducted for ferrierite material obtained from Tosoh Corporation whereas no pretreatment is conducted for ferrierite material obtained from Zeolyst Corp.

BRIEF DESCRIPTION OF THE DRAWINGS

[0016]FIG. 1(a-f) show NO and CO adsorption data collected by IR with (a) and (b) each being the spectra for prior art composition of Hansel (U.S. Pat. No. 5,524,432) and (c), (d), (e) and (f) being the spectra for materials of the present invention.

DETAILED DESCRIPTION

[0017] The present invention is concerned with a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material, e.g., hydrocarbons. The present invention is also concerned with compositions of matter useful in a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and hydrocarbons.

[0018] The term “NO_(x)” as used herein refers to nitrogen oxides and includes both nitrogen monoxide and nitrogen dioxide. The term “hydrocarbons” as used herein refers to not only hydrocarbons in a narrow sense but also partially oxidized products thereof such as oxygenated hydrocarbons, for example, alcohols and ketones.

[0019] Exhaust Gases

[0020] The exhaust gases which can be treated in the catalytic system of the present invention can come from the combustion of fuels in automotive engines, gas turbines, engines using an oxygen-rich mixture (lean-burn conditions), and power stations. The fuels can be, e.g., natural gas, gasoline, LPG, kerosene, heavy oil and coal. The exhaust gases typically include NO_(x) and O₂ as well as SO_(x), CO, CO₂, H₂, H₂O and hydrocarbons including methane and other lower hydrocarbons.

[0021] In performance testing of the catalysts and processes of the present invention, a simulated exhaust gas mixture was used. The simulated exhaust gas mixture included 75 ppm NO, 600 ppm HC (as C₁), 600 ppm CO, 200 ppm H₂, 12 percent 02, 5 percent CO₂, with the remainder N₂. Optional simulated exhaust gas mixture could further include 5 percent H₂O in the mixture and/or 1.5 to 15 ppm SO₂. The hydrocarbon (HC) is typically a propylene/propane mixture (1:1 mole ratio) although a mixture of propylene/octane mixture (1:1 mole ratio) may be used as well. Those skilled in the art will readily recognize that other variations of such simulated exhaust gas mixtures could be employed. For example, the hydrocarbon is generally present as a reductant material and can be replaced by other suitable reductant materials such as ammonia and the like.

[0022] Process Conditions

[0023] The exhaust gas is typically treated in the catalytic system of this invention at a temperature of from about 150° C. to about 900° C. or more, preferably at a temperature of from about 200° C. to about 650° C., and at a gas hourly space velocity, GHSV, (volumes of gas at STP per volume of catalyst per hour) adjusted to provide the desired conversion. The GHSV can be from about 1000 to about 500,000 hr⁻¹ preferably within the range of from about 2500 to about 250,000 hr⁻¹. The process of this invention is operable at subatmospheric to superatmospheric pressure, e.g., at from about 5 psia to about 500 psia, preferably from about 10 psia to about 50 psia, i.e., near or slightly above atmospheric pressure.

[0024] Adequate conversion may be readily achieved with a simple stationary fixed-bed of catalyst. However, other contacting means are also contemplated, such as contacting with a fluid bed, a transport bed, and a monolithic structure such as a honeycomb.

[0025] Catalyst Composition

[0026] Catalysts useful in this invention typically comprise small pore aluminosilicate zeolites whether naturally occurring or synthetic crystalline zeolites. Such zeolites further include a minor amount of a metal added to the zeolite framework. The preferred zeolites are related as being members of the family of 10-ring/8-ring zeolites that contain 10-ring pore openings with 8-ring side pockets or intersecting channels. Specific examples of these zeolites include ferrierite (FER) including ZSM-35 (U.S. Pat. No. 4,016,245), cobalt-gallium-phosphate-5 (CGF), cobalt-gallium-phosphate-6 (CGS), dachiardite (DAC), epistilbite (EPI), heulandite (HEU), ZSM-57 (U.S. Pat. No. 4,046,685) (MFS), stilbite (STI), wenkite (WEN), and weinebeneite (WEI) and other framework topologies such as SUZ-4 as described in U.S. Pat. No. 5,118,483. The three letter designations for the zeolites is in accordance with the IUPAC rules on Zeolite nomenclature, see, “Chemical Nomenclature and Formulation of Compositions of Synthetic and Natural Zeolites”, R. M. Barrer, Pure and Applied Chemistry, vol. 51, pp. 1091-1100 (1979). The family of 12-ring/8-ring zeolites may be used as well and includes SAPO-40 (AFR), MAPSO-46 (AFS), CoAPO-50 (AFY), beryllophosphate-H (BPH), gmelinite (GME), mazzite (MAZ), mordenite (MOR), and offretite (OFF). These zeolites and their isotypes are described in “Atlas of Zeolite Structure Types”, eds. W. H. Meier, D. H. Olson and Ch. Baerlocher, Elsevier, 4th Edition, 1996, which is hereby incorporated by reference. Among the preferred catalysts are included ferrierite materials (FER) such as that supplied by Tosoh Corporation as product number # HSZ-720KOA (lot # 5001 with a silica to alumina ratio of 17.7 mol/mol) and such as that supplied by Zeolyst Corp. as product # CP914B-20 (lot #52D with a silica to alumina ratio of 15.7 mol/mol).

[0027] Catalyst Pre-Treatment

[0028] The ferrierite material can be pre-treated by washing or soaking in a dilute ammonium fluoride solution at temperatures of from about 10° C to about 50° C., preferably from about 20° C. to about 35° C. for from about 2 hours to about 96 hours, preferably from about 4 hours to about 60 hours. Treatment with the selected pre-wash can be repeated with fresh wash solution for an additional period of time from about 2 hours to about 96 hours, preferably from about 4 hours to about 60 hours. Treatment at temperatures of as high as 60° C. have been found to yield poor catalytic performance in the conversion of NO_(x). The dilute ammonium fluoride solution can typically be from about 0.01 Molar (M) to about 2 M, preferably from about 0.05 M to about 1 M. Other solutions than ammonium fluoride may be used, e.g., solutions of ammonium nitrate, ammonium chloride, hydrochloric acid, nitric acid, hydrofluoric acid, oxalic acid and the like, although dilute solutions of ammonium fluoride are preferred. It has been found especially beneficial to pretreat ferrierite material obtained from Tosoh Corp. as product number # HSZ-720KOA (lot #5001 with a silica to alumina ratio of 17.7 mol/mol) with the ammonium fluoride pretreatment. In contrast, some ferrierite materials such as product # CP914B-20 (lot #52D with a silica to alumina ratio of 15.7 mol/mol) obtained from Zeolyst Corp. have been found (after suitable metal loading) to exhibit high catalytic conversion rates at low temperatures without any such pretreatment. Both materials, i.e., the Tosoh ferrierite with the above pretreatment and the Zeolyst ferrierite without pretreatment, were found to exhibit surprisingly exceptional NO_(x) conversion rates at catalyst temperatures as low as about 200° C. to about 300° C. or even lower.

[0029] Metal Treatment

[0030] After any desired pre-treatment, the ferrierite materials are generally calcined by heating at temperatures from about 450° C. to about 650° C. for from about 2 hours to about 10 hours. While not wishing to be bound by the present explanation, it is believed that such a calcination is generally preferred as it converts ammonium ions to hydrogen ions in the zeolite pore structure. Surprisingly, it has been found that calcination was not needed with Tosoh ferrierite material when the added metal is either gallium or indium although calcination is necessary for the same ferrierite material when the added metal is only cobalt.

[0031] Following calcination, the ferrierite is treated with a metal salt to enhance the catalytic performance. The metal salt can generally include any transition metal or other non-alkali metal or non-alkaline earth metal or combination of such metals as is well know to those of skill in the art. Among the preferred metal salts are a cobalt salt, a gallium salt, an indium salt, a manganese salt or a zinc salt. The loading of the cobalt metal upon a zeolite catalyst material such as a ferrierite material can be readily accomplished by an aqueous exchange process. A dilute aqueous solution of a metal salt is added to the ferrierite material and stirred for a desired amount of time. The metal solution is centrifuged off, changed if desired, and the addition, stirring, and centrifuging repeated. The zeolite is rinsed with deionized water and dried at 110° C. Optionally, a solid state exchange process may be used. A volatile metal halide is ground in a mortar and pestle with ferrierite material, heated under a vacuum to between about 500° C. and about 700° C. for from about 1 hour to about 12 hours, washed with deionized water and dried, e.g., at 110° C. Typical metal loading levels range from as low as about 0.02 weight percent to as high as about 2.0 weight percent or higher, based on total weight of metal and zeolite material. Higher metal loadings may be used but are generally not beneficial. With Tosoh ferrierite material, metal loadings nearer to the top of the range from 0.02 to 2 weight percent have been found preferable. With Zeolyst ferrierite material, metal loadings less than about 0.1 weight percent have been found preferable.

[0032] N₂O:

[0033] An additional advantage of these materials is that they do not catalyze the formation of N₂O (nitrous oxide) from the exhaust gas mixture. Other more conventional lean NO_(x) catalysts, particularly those containing platinum group metals, are known to form copious amounts of nitrous oxide.

[0034] Other metals, and combinations:

[0035] Other metal ions in addition to Co have been shown to be active for NO_(x) catalysis in FER. For example, Mn-exchanged ferrierite can be prepared that has similar activity to the best Co ferrierite catalysts described here. Also, Ga-exchanged ferrierite and In-exchanged ferrierite can be prepared that have similar activity to the Co ferierite catalysts described here. Other metal ions including Fe, Ni, Cu, Cr, and Ag can also lead to active ferrierite catalysts. It is well known in the field of catalysis that there are often synergistic effects of adding additional metal ion components to a catalyst, or by exchanging multiple metal ions into a catalyst to improve catalytic performance. In this regard, the combination of metal ions such as Ga and In in addition to those listed above can be added to the Co catalyst to modify the catalytic performance of the ferrierite catalysts. Combinations of Co and Ga, Co and In, and Co, Ga and In have demonstrated high catalytic activity with a broad temperature window. Other metals and combinations will be readily apparent to those skilled in the art.

[0036] Catalysts for reduction of NO_(x) levels in exhaust gases need to have high activity and high temperature stability in the presence of both oxygen and water vapor.

[0037] Evaluation of catalytic activity was as follows. Catalytic material was sieved into 20-30 mesh particle size. Icc (ca. 0.5 g) of material was placed into a quartz tube reactor and supported with a coarse quartz frit. A simulated gas exhaust mixture having the composition NO=75 ppm, HC=600 ppm (1:1 propylene:propane for screening—see above for other variations), CO=600 ppm, H₂=200 ppm, O₂=12%, and CO₂=5% was passed through the reactor at a flow rate of approximately 400 milliliters/minute (25,000 h⁻¹ of GHSV (gas hourly space velocity)). The gas mixture was delivered by blending 3 mixes through mass flow controllers (MFC) at equal rates, totaling about 400 milliliters/minute; MFC 1=H₂, propylene, propane in N₂; MFC 2=NO in N₂; MFC 3=CO, CO₂, O₂ in N₂. The catalyst bed was heated to approximately 300° C. under the CO/CO₂/O₂ mixture. The remaining two mixtures were turned on, and the reactor was heated to 600° C. and held for 20 minutes. Starting at 600° C., the temperature was ramped down and held at various desired temperatures (50° C. increments) for 20 minutes each down to 100° C. Conversion data points were collected every minute.

[0038] The compositions of matter of the present invention have been evaluated or tested under the above conditions and have exhibited higher NO_(x) conversion levels than an exemplary prior art composition tested in the same manner. While numerous prior patents have often tested for NO_(x) conversion under widely varying conditions, the compositions of matter of the present invention exhibit high NO_(x) conversion levels of generally at least about 60 percent at temperatures from 200° C. to 400° C. under the above specified test conditions.

[0039] While not wishing to be bound by the present explanation, it is believed that the activity of the small pore aluminosilicate catalysts described here exhibit unusually high activity over a broad temperature range because of the adsorption properties of small pore zeolites. These adsorption properties lead to the ability to store both hydrocarbons and NO_(x) at low temperatures (at or below about 200° C.), and then to release them at higher temperatures (at or above around 150° C.) where catalytic conversion of the NO_(x) and hydrocarbons may take place in the usual manner. The hydrocarbon adsorption properties also lend a mechanism to control the catalytic combustion of the hydrocarbons, and provide for a much wider temperature range over which catalytic combustion may occur. In turn, the broad range of catalytic combustion of the hydrocarbons means that the unburned hydrocarbons may be available in their role as a reductant for NO_(x) over a much broader range than a conventional catalyst. The tailoring of the hydrocarbon and NO_(x) adsorption properties by choosing and tailoring the topological and chemical properties of small pore zeolites allows for optimization of the temperature of operation and the temperature range of catalytic activity of the catalyst.

[0040] The present invention is more particularly described in the following examples, which are intended as illustrative only, since numerous modifications and variations will be apparent to those skilled in the art. The ferrierite material in the examples was supplied by either Tosoh Corporation as product number # HSZ-720KOA (lot #5001 with a silica to alumina ratio of 17.7 mol/mol) or Zeolyst Corp. as product # CP914B-20 (lot #52D with a silica to alumina ratio of 15.7 mol/mol).

EXAMPLE 1

[0041] Approximately 5 grams of Tosoh ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 2

[0042] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at room temperature. The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 4.2 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.23 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 9.4 and the ratio of Al:Co was analyzed as 36.8.

EXAMPLE 3

[0043] Approximately 22 grams of Tosoh ferrierite was added to 250 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at room temperature. The mixture was then centrifuged, the supernatant was discarded, and another 200 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 48 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 72 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.43 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 9.2 and the ratio of Al:Co was analyzed as 19.8.

EXAMPLE 4

[0044] Approximately 20 grams of Tosoh ferrierite was added to 200 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at room temperature. The mixture was then centrifuged, the supernatant was discarded, and another 200 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 6 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 250 mL of a 0.01M cobalt (II) acetate solution and stirred for 48 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 250 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 72 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried cobalt ferrierite material was finally calcined under flowing dry air for 6 hours at 600° C. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 1.01 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 8.7 and the ratio of Al:Co was analyzed as 7.9.

EXAMPLE 5

[0045] Approximately 22 grams of Tosoh ferrierite was added to 250 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at room temperature. The mixture was then centrifuged, the supernatant was discarded, and another 250 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at 60±2° C. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at 60±2° C., then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 1.33 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 9.1 and the ratio of Al:Co was analyzed as 6.5.

EXAMPLE 6

[0046] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at 60±5° C. The mixture was then centrifuged, the supernatant was discarded, and another 100 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at 60±5° C., then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 4.5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.24 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 9.5 and the ratio of Al:Co was analyzed as 35.0.

EXAMPLE 7

[0047] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at 60±5° C. The mixture was then centrifuged, the supernatant was discarded, and another 100 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at 60±5° C., then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 4 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at 60±2° C. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at 60±2° C., then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 1.4 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 9.8 and the ratio of Al:Co was analyzed as 5.8. TABLE 1 Percentage of NO_(x) conversion at various catalyst temperatures for Tosoh ferrierite versus variations in cobalt composition, pre-treatment conditions and cobalt exchange conditions. The pre-treatment was two washes with 0.1M ammonium fluoride at room temperature, and the cobalt treatment was two exchanges with 0.01M cobalt acetate at room temperature, unless otherwise noted. Varied Conditions and Cobalt 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. Composition Run 1 12 25 35 27 45 50 No pre- treatment Run 2 92 100 95 85 72 52 (0.23 wt. % Co) Run 3 95 98 95 85 80 75 (0.43 wt. % Co) Run 4 75 95 100 98 95 100 (1.01 wt. % Co) Run 5 45 65 85 92 95 98 60° C. Co exchange (1.33 wt. % Co) Run 6 92 95 95 82 70 58 60° C. NH₄F washes (0.24 wt. % Co) Run 7 40 55 50 30 40 75 60° C. NH₄F washes and 60° C. Co exchange (1.4 wt. % Co)

[0048] The results of Table 1 indicate that increasing the cobalt loading up to about 1 weight percent broadens NO_(x) conversion to a wider temperature range. Run 7 in comparison to run 5 shows that higher temperature pre-treatment washes with ammonium fluoride were not not beneficial to NO_(x) conversion.

EXAMPLE 8

[0049] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.061 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 9.4 and the ratio of Al:Co was analyzed as 124.5.

EXAMPLE 9

[0050] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M manganese (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the manganese (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The manganese-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.077 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 9.8 and the ratio of Al:Co was analyzed as 91.8.

EXAMPLE 10

[0051] Approximately 22 grams of Zeolyst ferrierite was added to 250 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at room temperature. The mixture was then centrifuged, the supernatant was discarded, and another 250 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.023 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 10.5 and the ratio of Al:Co was analyzed as 339.8.

EXAMPLE 11

[0052] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at 60±2° C. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at 60±2° C., then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 12

[0053] Approximately 10 grams of Zeolyst ferrierite was added to 100 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at 60±2° C. The mixture was then centrifuged, the supernatant was discarded, and another 100 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at 60±2° C., then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Approximately 4.5 grams of the ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.095 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 11.3 and the ratio of Al:Co was analyzed as 83.4.

EXAMPLE 13

[0054] Approximately 10 grams of Zeolyst ferrierite was added to 100 mL of a 0.1M ammonium fluoride solution. The mixture was stirred for 24 hours at 60±2° C. The mixture was then centrifuged, the supernatant was discarded, and another 100 mL portion of the ammonium fluoride solution was added to the ferrierite. This mixture was stirred for another 24 hours at 60±2° C., then centrifuged, and the supernatant was again discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Approximately 5 grams of the ferrierite material was added to 200 mL of a 0.1M cobalt (II) acetate solution and stirred for 24 hours at 60±2° C. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at 60±2° C., then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 0.29 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 11.9 and the ratio of Al:Co was analyzed as 24.7.

EXAMPLE 14

[0055] Approximately 5 grams of Zeolyst ferrierite was mixed with approximately 0.5 gram of cobalt (II) iodide with a mortar and pestle. This mixture was placed into a quartz tube and put under vacuum. The ferrierite mixture was heated to 120° C. and held at that temperature for approximately 50 minutes. The mixture was then heated to 500° C. and held for approximately 1 hour. The cobalt-exchanged ferrierite was cooled to room temperature under vacuum before being removed from the tube. The cobalt ferrierite was then washed with a series of three aliquots of deionized water and finally dried at 110° C. overnight. Elemental analysis of the cobalt-exchanged ferrierite material showed that the content of cobalt was 1.65 weight percent based on the total weight of cobalt-exchanged ferrierite material. The ratio of Si:Al was analyzed as 10.4 and the ratio of Al:Co was analyzed as 4.7. TABLE 2 Percentage of NO_(x) conversion at various catalyst temperatures for Zeolyst ferrierite versus variations in cobalt composition, pre-treatment conditions and cobalt exchange conditions. The pre-treatment was two washes with 0.1M ammonium fluoride at room temperature, and the cobalt treatment was two exchanges with 0.01M cobalt acetate at room temperature, unless otherwise noted. Varied Conditions and Cobalt 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. Composition Run 8 100 100 95 87 85 87 No pre- treatment (0.061 wt. % Co) Run 9 100 100 90 82 75 85 Manganese, no pre- treatment (0.077 wt. % Mn) Run 10 100 100 92 80 65 57 (0.023 wt. % Co) Run 11 92 98 92 75 65 52 60° C. Co exchange Run 12 97 98 95 65 50 45 60° C. NH₄F washes (0.095 wt. % Co) Run 13 85 90 85 75 65 60 60° C. Co exchange, 60° C. NH₄F washes (0.29 wt. % Co) Run 14 98 100 98 90 85 70 No pre- treatment, solid-state Co exchange (1.65 wt. % Co)

[0056] The results of Table 2 indicate that high cobalt loading is not necessary for high NO_(x) conversion with the Zeolyst ferrierite material and that loadings of less than 0.1 wt % can provide high NO_(x) conversion. In addition, Runs 8 and 9 demonstrate that high NO_(x) conversion can be obtained without any pre-treatment.

EXAMPLE 15a

[0057] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 1M ammonium fluoride solution. The mixture was stirred for 24 hours at room temperature.

[0058] The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 15b

[0059] Preparation was the same as Example 15a with the difference that the ammonium fluoride solution was 0.1M and there were two separate ammonium fluoride washes.

[0060] EXAMPLE 16a Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 1M ammonium chloride solution. The mixture was stirred for 24 hours at room temperature.

[0061] The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 16b

[0062] Preparation was the same as Example 16a with the difference that the ammonium chloride solution was 0.1M and there were two separate ammonium fluoride washes.

[0063] EXAMPLE 17a Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a IM ammonium nitrate solution. The mixture was stirred for 24 hours at room temperature.

[0064] The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 17b

[0065] Preparation was the same as Example 17a with the difference that the ammonium nitrate solution was 0.1M and there were two separate ammonium fluoride washes. TABLE 3 Percentage of NO_(x) Conversion at Various Catalyst Temperatures for Tosoh ferrierite versus variations in wash composition (NH₄F versus other NH₄ ⁺ salts) where the pre-treatment was one 24-hour wash with the 1.0 M NH₄ ⁺ salt at room temperature and two 24-hour washes with the 0.1 M NH₄ ⁺ salt. 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. Salt Run 15a 92 95 98 90 80 75 NH₄F Run 15b 95 97 92 80 65 52 NH₄F Run 16a 82 87 85 75 60 50 NH₄Cl Run 16b 90 90 82 67 65 65 NH₄Cl Run 17a 100 100 95 90 80 70 NH₄NO₃ Run 17b 92 95 87 60 30 15 NH₄NO₃

[0066] The results of Table 3 demonstrate that pretreatment with the fluoride anion yielded a broader conversion window than the nitrate anion. Also, the results suggest that lower pre-treatment concentrations may be preferable for some ionic species.

EXAMPLE 18

[0067] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 0.5M ammonium fluoride solution. The mixture was stirred for 4 hours at room temperature.

[0068] The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 19

[0069] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 0.5M oxalic acid solution. The mixture was stirred for 4 hours at room temperature. The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 20

[0070] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 0.5M nitric acid solution. The mixture was stirred for 4 hours at room temperature. The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 21

[0071] Approximately 10 grams of Tosoh ferrierite was added to 100 mL of a 0.5M hydrochloric acid solution. The mixture was stirred for 4 hours at room temperature. The mixture was then centrifuged and the supernatant was discarded. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite material was finally calcined under flowing dry air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. TABLE 4 Percentage of NO_(x) Conversion at Various Catalyst Temperatures for Tosoh ferrierite versus variations in wash composition (NH₄F versus acids) where the pre-treatment was one 4-hour wash with the 0.5M NH₄F or acid at room temperature Varied Condi- 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. tions Run 100 100 95 85 75 70 NH₄F 18 Run 40 55 67 70 85 98 Oxalic 19 acid Run 70 85 90 90 85 95 HNO₃ 20 Run 55 72 82 80 90 100 HCl 21

[0072] The results of Table 4 demonstrate that NO_(x) conversion is substantially better for pre-treatment with ammonium fluoride for the low temperature ranges of 200° C. to 300° C.

EXAMPLE 22 (COMPARATIVE EXAMPLE-PRIOR ART)

[0073] Example 4 of Hansel, U.S. Pat. No. 5,524,432 was prepared for comparison to the compositions of matter of the present invention. Approximately 15 grams of Tosoh ferrierite was added to 180 mL of a 1.0M ammonium nitrate solution. The mixture was stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 180 mL of the ammonium nitrate solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. A third ammonium nitrate wash was performed similarly. The ferrierite was then washed once with 1L of deionized water and dried at 110° C. overnight. Approximately 10 grams of the dried ferrierite material was added to 500 mL of deionized water. This solution was added to a solution of 500 mL of deionized water and 4 grams of cobalt (II) acetate tetrahydrate. The mixture was heated to 80° C. and stirred for 24 hours.

[0074] The mixture was centrifuged and the supernatant was discarded. The ferrierite material was again mixed with 500 mL of deionized water and added to another 500 mL of the cobalt (II) acetate solution. The mixture was again heated to 80° C., stirred for 24 hours, centrifuged and decanted. The cobalt-exchanged ferrierite was then washed once with IL of deionized water and dried at 110° C. overnight.

[0075] IR measurements of this final product prepared in accordance with Hansel were taken. FIG. 1(a) shows the IR spectra of the material under 1 Torr of NO at room temperature. FIG. 1(b) shows the IR spectra of the material after exposure to CO and subsequent evacuation of CO at a temperature of 120 K. Peak positions and relative intensities are shown in Table 8.

EXAMPLE 23

[0076] Approximately 15 grams of Tosoh ferrierite was added to 180 mL of a 1.0M ammonium fluoride solution. The mixture was stirred for 24 hours at room temperature.

[0077] The mixture was centrifuged, the supernatant was discarded, and another 180 mL of the ammonium fluoride solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. A third ammonium fluoride wash was performed similarly. The ferrierite was then washed once with 1L of deionized water and dried at 110° C. overnight. Approximately 10 grams of the dried ferrierite material was added to 500 mL of deionized water. This solution was added to a solution of 500 mL of deionized water and 4 grams of cobalt (II) acetate tetrahydrate. The mixture was heated to 80° C. and stirred for 24 hours., The mixture was centrifuged and the supernatant was discarded. The ferrierite material was again mixed with 500 mL of deionized water and added to another 500 mL of the cobalt (II) acetate solution. The mixture was again heated to 80° C., stirred for 24 hours, centrifuged and decanted. The cobalt-exchanged ferrierite was then washed once with 1L of deionized water and dried at 110° C. overnight.

EXAMPLE 24

[0078] Approximately 15 grams of Tosoh ferrierite was added to 180 mL of a 1.0M ammonium nitrate solution. The mixture was stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 180 mL of the ammonium nitrate solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. A third ammonium nitrate wash was performed similarly. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Approximately 5 grams of the dried ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL of the cobalt (II) acetate solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 25

[0079] Approximately 15 grams of Tosoh ferrierite was added to 180 mL of a 1.0M ammonium nitrate solution. The mixture was stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 180 mL of the ammonium nitrate solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. A third ammonium nitrate wash was performed similarly. The ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The dried ferrierite was calcined under dry flowing air for 10 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL of the cobalt (II) acetate solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. TABLE 5 Percentage of NO_(x) conversion at various catalyst temperatures for Tosoh ferrierite versus variations in pre-treatment and cobalt exchange. 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. Run 22 50 82 100 95 85 70 NH₄NO₃ washed, uncalcined, 80° C. Co exchange Run 23 47 80 100 100 100 85 NH₄F washed, uncalcined, 80° C. Co exchange Run 24 70 75 65 57 57 57 NH₄NO₃ washed, uncalcined, room temp. Co exchange Run 25 97 100 95 57 35 25 NH₄NO₃ washed, calcined, room temp. Co exchange

[0080] The results of Table 5 demonstrate that calcination as in Run 25 is generally better for low temperature activity at 300° C. or lower. Also, Run 23 shows a broad NO_(x) reduction window.

[0081] Examples 26-31 compare the performance of catalysts prepared with the metals of cobalt, gallium and indium. EXAMPLE 26

[0082] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 27

[0083] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M gallium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M gallium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 28

[0084] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M indium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M indium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 29

[0085] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt/gallium-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 30

[0086] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M indium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/0.01M indium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt/indium-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. EXAMPLE 31

[0087] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate/0.01M indium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate/0.01M indium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt/gallium/indium-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. TABLE 6 Percentage of NO_(x) conversion at various catalyst temperatures for Zeolyst ferrierite versus metal ion. No pre-treatment was performed on the Zeolyst ferrierite. 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. 500° C. 600° C. metal Run 26 100 100 95 60 45 37 37 37 Co Run 27 100 100 100 100 95 95 95 47 Ga Run 28 97 100 100 100 100 100 100 80 In Run 29 100 100 100 95 95 100 100 100 Co, Ga Run 30 100 100 100 95 100 100 95 45 Co, In Run 31 100 100 100 100 100 100 100 80 Co, Ga, In

[0088] The results of Table 6 show the broad NO_(x) reduction window of Runs 27-31.

EXAMPLE 32

[0089] Approximately 5 grams of Tosoh ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 33

[0090] Approximately 5 grams of Tosoh ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/gallium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 34

[0091] Approximately 5 grams of Tosoh ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate 0.01M indium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/indium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 35

[0092] Approximately 5 grams of Tosoh ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate/0.01M indium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/gallium (III) nitrate/indium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 36

[0093] Approximately 20 grams of Tosoh ferrierite was added to 200 mL of a 0.1M ammonium fluoride solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL of the ammonium fluoride solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. The ferrierite material was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. The ferrierite was calcined under dry flowing air for 6 hours at 600° C. Approximately 5 grams of the calcined ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 37

[0094] Approximately 20 grams of Tosoh ferrierite was added to 200 mL of a 0.1M ammonium fluoride solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL of the ammonium fluoride solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. The ferrierite material was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Approximately 5 grams of the dried ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/0.01M gallium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt/gallium-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 38

[0095] Approximately 20 grams of Tosoh ferrierite was added to 200 mL of a 0.1M ammonium fluoride solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL of the ammonium fluoride solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. The ferrierite material was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

[0096] Approximately 5 grams of the dried ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M indium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/0.01M indium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt/indium-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 39

[0097] Approximately 20 grams of Tosoh ferrierite was added to 200 mL of a 0.1M ammonium fluoride solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL of the ammonium fluoride solution was added to the ferrierite. The mixture was again stirred for 24 hours at room temperature, centrifuged and decanted. The ferrierite material was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. Approximately 5 grams of the dried ferrierite material was added to 200 mL of a 0.01M cobalt (II) nitrate/0.01M indium (III) nitrate/0.01M indium (III) nitrate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.01M cobalt (II) nitrate/0.01M indium (III) nitrate/0.01M indium (III) nitrate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt/gallium/indium-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

[0098] It should be noted that the calcining step was not found necessary with Ga or In materials, whereas it was important with the Co-FER materials. TABLE 7 Percentage of NO_(x) conversion at various catalyst temperatures for Tosoh ferrierite versus metal ion. Pre-treatment of the ferrierite was two 0.1M ammonium fluoride washes, unless otherwise noted. 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. 500° C. 600° C. Run 32 15 25 37 32 35 52 45 15 No pre- treatment, Co Run 33 92 97 100 100 85 70 52 42 No pre- treatment, Co and Ga Run 34 67 75 90 100 82 75 82 57 No pre- treatment, Co and In Run 35 87 92 100 100 100 100 100 85 No pre- treatment, Co, Ga and In Run 36 97 100 95 82 70 60 55 40 Co Run 37 100 100 100 100 100 100 100 92 Co, Ga Run 38 95 100 100 100 100 100 100 60 Co, In Run 39 100 100 100 100 100 100 100 80 Co, Ga, In

[0099] The results of Table 6 show the broad NO_(x) reduction window of Runs 33-39.

[0100] Catalytic screening was conducted with and without a supported platinum catalyst bed directly downstream of the catalyst bed of the present invention. The platinum catalyst bed serves to completely react partially reduced nitrogen-containing species in order to obtain a NO_(x) conversion to N₂.

EXAMPLE 40 Cobalt Ferrierite (Zeolyst)

[0101] Approximately 5 grams of Zeolyst ferrierite material was added to 200 mL of a 0.1M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the 0.1M cobalt (II) acetate solution was added to the ferrierite material. The mixture was again stirred for 24 hours, centrifuged, and decanted. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight.

EXAMPLE 41 Cobalt Ferrierite (Zeolyst) with Supported Platinum Catalyst

[0102] In the catalyst testing apparatus, a supported platinum catalyst (obtained from Johnson-Matthey) was sieved and placed in the quartz tube reactor directly downstream of the ferrierite catalyst bed (example 40). Testing of the catalytic activity was carried out as in all other experiments.

EXAMPLE 42 Cobalt Gallium Ferrierite (Zeolyst) The material from Example 29 was tested for catalytic activity. EXAMPLE 43 Cobalt Gallium Ferrierite+Supported Platinum Catalyst

[0103] In the catalyst testing apparatus, a supported platinum catalyst (obtained from Johnson-Matthey) was sieved and placed in the quartz tube reactor directly downstream of the ferrierite catalyst bed of example 42. Testing of the catalytic activity was carried out as in all other experiments. TABLE 8 Percentage of NO_(x) conversion at various catalyst temperatures for Zeolyst ferrierite with and without a supported platinum catalyst bed directly downstream of the ferrierite catalyst bed. 200° C. 250° C. 300° C. 350° C. 400° C. 450° C. 500° C. 600° C. Run 100 100 95 85 80 82 82 65 Co, without 40 Pt bed Run 100 100 85 60 47 40 35 27 Co, with Pt 41 bed Run 100 100 100 95 95 100 100 100 Co and Ga, 42 without Pt bed Run 100 100 100 100 95 95 97 50 Co and Ga, 43 with Pt bed

[0104] The results of Table 8 show that the combination of Co and Ga of Runs 42 and 43 exhibit greater selectivity to NO_(x) conversion at lower temperatures than Co alone and with broader operating windows.

[0105] IR measurements for NO and CO adsorption data was conducted on material from example 22 (prior art), material from example 10 and a material prepared in the manner of example 8. The various spectra are shown in FIG. 1(a-f). Table 8 shows the various peak positions and relative intensities from the figures. TABLE 9 NO Under 1 Torr at Room After Exposure to and Evacuation of Temperature CO at 120K Sample Peak Position Relative Intensity Peak Position Relative Intensity Example 22 2175 0.53 2346 0.23 (prior art) 1933 0.39 2225 0.05 1898 0.32 2190 0.53 1813 1.00 2173 1.00 1591 0.00 2096 0.00 2042 0.22 Example 10 2169 1.00 2356 0.12 1933 0.19 2225 0.00 1876 0.24 2190 0.00 1813 0.00 2173 0.12 1591 0.27 2096 0.23 2049 1.00 In accordance 2175 1.00 2356 0.23 with Example 8 1933 0.19 2225 0.35 1876 0.19 2190 0.14 1813 0.19 2173 1.00 1591 0.00 2096 0.15 2049 0.73

[0106] Substantial differences in the IR spectra between a pre-treated Tosoh cobalt ferrierite sample and Zeolyst cobalt ferrierite materials (with either no pre-treatment or with pre-treatment) can be seen with both adsorbed NO and CO. In the NO spectra, the Tosoh material gives a very intense peak at 1813 cm⁻¹ and moderately intense peaks at 1933 cm⁻¹ and 1898 cm⁻¹, whereas these peaks are absent in both of the Zeolyst materials. The CO spectra yield relatively strong and broad peaks at around 2100 cm⁻¹ for both Zeolyst materials, and a relatively low intensity peak for the Tosoh material in the same region. Both of the pre-treated materials (Tosoh and Zeolyst) reveal relatively intense peaks in the 2225-2173 cm⁻¹ region of the CO spectra. A slight increase in intensity at 2346 cm⁻¹ can be seen for the Tosoh material over the Zeolyst materials.

EXAMPLE 44

[0107] Approximately 10 grams of Zeolyst ferrierite material was added to 400 mL of a 0.01M cobalt (II) acetate solution and stirred for 24 hours at room temperature. The mixture was centrifuged, the supernatant was discarded, and another 200 mL portion of the cobalt (II) acetate solution was added to the ferrierite. This mixture was stirred for 24 hours at room temperature, then centrifuged, and the supernatant was again discarded. The cobalt-exchanged ferrierite was then washed with a series of three aliquots of deionized water and dried at 110° C. overnight. TABLE 10 Ammonia as reductant screening test: replaced mass-flow controlled feed of hydrocarbon and hydrogen with 75 ppm NH₃, with and without 5% H₂O. 220° C. 290° C. 400° C. 600° C. Reductant Run 44a 100 100 87 65 Hydrocarbon Run 44b 50 55 40 5 Ammonia (1:1::NH₃:NO_(x)) Run 44c 20 50 45 0 Ammonia (1:1::NH₃:NO_(x)) with 5% H₂O

[0108] The results of Table 10 demonstrate that ammonia can also serve as a reductant material.

[0109] Although the present invention has been described with reference to specific details, it is not intended that such details should be regarded as limitations upon the scope of the invention, except as and to the extent that they are included in the accompanying claims. 

What is claimed is:
 1. A process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material comprising: contacting said gas stream under conditions effective to catalytically reduce said nitrogen oxides with a catalyst comprising an aluminum-silicate type material and a metal in an amount of up to about 0.1 weight percent based on total weight of catalyst, said catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 60 percent under temperatures within the range of from about 200° C. to about 400° C.
 2. The process of claim 1 wherein said exhaust gas stream is characterized as oxygen rich.
 3. The process of claim 1 wherein said aluminum-silicate type material is characterized as including 10-ring/8-ring zeolite materials or 12-ring/8-ring zeolite materials.
 4. The process of claim 3 wherein said aluminum-silicate type material is selected from the group consisting of FER, CGF, CGS, DAC, EPI, HEU, MFS, STI, WEN, WEI, AFR, AFS, AFY, BPH, GME, MAZ, MOR, OFF, and SUZ-4.
 5. The process of claim 1 wherein said aluminum-silicate type material is a ferrierite material.
 6. The process of claim 1 wherein said aluminum-silicate type material is a ferrierite material further including the metal.
 7. The process of claim 1 wherein the metal is selected from the group consisting of cobalt, indium, gallium, manganese and combinations thereof.
 8. A process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material comprising: contacting said gas stream under conditions effective to catalytically reduce said nitrogen oxides with a catalyst, the catalyst comprising an aluminum-silicate type material and a metal in an from about 0.1 weight percent to about 7.0 weight percent, the aluminum-silicate type material amount having been pretreated prior to contact with said exhaust gas stream by contact with a dilute solution of a material selected from the group consisting of ammonium fluoride, ammonium nitrate, ammonium chloride, nitric acid, hydrochloric acid, hydrofluoric and oxalic acid for a sufficient period of time followed by addition of a metal to said pre-treated ferrierite material to allow for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material, said catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 50 percent under temperatures within the range of from about 200° C. to about 600° C.
 9. The process of claim 8 wherein said aluminum-silicate type material is a ferrierite material further including a minor amount of a metal selected from the group consisting of cobalt, indium, gallium, manganese and combinations thereof.
 10. The process of claim 9 wherein said dilute solution is of ammonium fluoride.
 11. A composition of matter, useful in a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material, comprising a zeolite material having undergone a pretreatment including contact with a dilute solution of a material selected from the group consisting of ammonium fluoride, ammonium nitrate, ammonium chloride, nitric acid, hydrochloric acid, hydrofluoric and oxalic acid for a sufficient period of time followed by addition of a metal to said pretreated ferrierite material to allow for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by at least 60 percent under temperatures within the range of from about 200° C. to about 600° C.
 12. The composition of claim 11 wherein said metal is selected from the group consisting of cobalt, indium, gallium, manganese and combinations thereof.
 13. The composition of claim 11 wherein said zeolite material is a ferrierite.
 14. A composition of matter, useful in a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material, comprising a zeolite material including a metal in an amount of up to about 0.1 weight percent based on total weight of zeolite and metal, said composition characterized by catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by at least 60 percent under temperatures within the range of from about 200° C. to about 400° C.
 15. The composition of claim 14 wherein said metal is selected from the group consisting of cobalt, indium, gallium, manganese and combinations thereof.
 16. The composition of claim 14 wherein said zeolite material is a ferrierite.
 17. The composition of claim 16 wherein the metal is a combination of at least two of cobalt, indium and gallium and said composition characterized by catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by at least 80 percent under temperatures within the range of from about 200° C. to about 400° C. 